Visible light-induced catalytic hydrosilylation of ketones mediated by manganese NHC complexes

Manganese catalysis has attracted significant attention in the last few years. In comparison with the extensively studied Mn complexes bearing phosphine-based pincer ligands, catalysis with Mn containing N-heterocyclic carbenes (NHC) is poorly developed. In this work, new manganese(I) complexes bearing an NHC ligand with picolyl wingtip substituents (an N,C,N ligand) have been synthesized and fully […]

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